Extraction kinetics of cobalt and manganese with D2EHPA from lithium-ion battery recyclate

نویسندگان

چکیده

The separation of manganese from cobalt sulfate solutions is crucial in the field spent lithium-ion battery recycling. A membrane-based microreactor used to reveal required mass transfer characteristics as diffusion and chemical reaction. dependence di-(2-ethylhexyl)phosphoric acid (D2EHPA) concentration, pH, metal ion concentration on extraction efficiency are investigated. back-reaction term introduced giving a significant influence effective rate even at small complex concentrations initial rates proved be inaccurate describe system. It shown that pH 3.0 mainly diffusive while strongly kinetically controlled. At separating 3.9 good agreement between model experimental data only given if equilibrium back-extraction considered (deviation less than 5%).

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ژورنال

عنوان ژورنال: Chemical engineering research & design

سال: 2022

ISSN: ['1744-3563', '0263-8762']

DOI: https://doi.org/10.1016/j.cherd.2022.01.005